Daisuke Sakamoto

Research interest Organic catalysis Related Publication and Patents 4. One-Pot Synthesis of (R)-Baclofen via Aldol Condensation of Acetaldehyde with Diphenylprolinol Silyl Ether Mediated Asymmetric Michael Reaction as a Key Step Yujiro Hayashi, Daisuke Sakamoto, and Daichi Okamura 3. Asymmetric Mannich reaction of alpha-keto imines catalyzed by diarylprolinol silyl ether. Hayashi Y, Sakamoto D, Shomura H, Hashizume D. Chem. Eur. J., 19, 7678 (2013). 2. One-Pot Synthesis of Chiral Aziridines by a Domino Reaction by Using Desulfonylative Formation on the N-Tosyl Imine of Chloroacetaldehyde with an Asymmetric Mannich Reaction as a Key step Y. Hayashi, T. Urushima, D. Sakamoto, K. Torii and H. Ishikawa Chem. Eur. J., 17, 11715 (2011). 1. Enantio- and Diastereoselective Synthesis of Piperidines by Coupling of Four Components in a "One-Pot" Sequence Involving Diphenylprolinol Silyl Ether Mediated Michael Reaction T. Urushima, D. Sakamoto, H. Ishikawa, and Y. Hayashi Org.Lett., 12, 4588 (2010). Comments

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